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Question
Chemistry
The amount of current in Faraday is required for the reduction of 1 mol of Cr2O72- ions to Cr3+ is,
Q. The amount of current in Faraday is required for the reduction of 1 mol of
C
r
2
O
7
2
−
ions to
C
r
3
+
is,
5189
209
KCET
KCET 2016
Electrochemistry
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A
1 F
14%
B
2 F
19%
C
6 F
58%
D
4 F
8%
Solution:
(
+
C
)
C
r
2
O
7
2
−
⟶
(
+
3
)
C
r
3
+
:
Oxidation number of
C
r
It shows change in oxidation number, i.e. change of 3 moles of electrons per mole of Cr-atom.
∵
C
r
2
O
7
2
−
has 2 moles of Cr-atoms. Hence, total 6 moles of electrons, i.e.
6
F
of charge (current) is required for reduction of 1 mole of
C
r
2
O
7
2
−
ions.