Different complex ions have the same molecular formula. Ligands are interchanged between the complex cation and complex anion. These type of complexes are called coordination isomers.
In [Pt(NH3)4][CuCl4], ammonia ligands are attached to Pt metal and chloride ligands are attached to Cu metal.
In [Cu(NH3)4][PtCl4], ammonia ligands are attached to Cu metal and chloride ligands are attached to P t metal.