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Tardigrade
Question
Chemistry
Predict the correct intermediate and product in the following reaction H3C-C≡ CH oversetH2 O , H2 S O4 arrow underset(. X .)i n t e r m e d i a t e arrow underset(. Y .)p r o d u c t
Q. Predict the correct intermediate and product in the following reaction
H
3
C
−
C
≡
C
H
→
H
2
O
,
H
2
S
O
4
(
X
)
in
t
er
m
e
d
ia
t
e
→
(
Y
)
p
ro
d
u
c
t
126
167
NTA Abhyas
NTA Abhyas 2022
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A
B
C
D
Solution:
Here first addition reaction occurs according to Markonikov reaction than tautomerisation occurs to give acetone as follows
(
H
)
3
C
−
C
≡
CH
→
(
H
)
2
O
(
CH
)
3
OH
∣
−
C
=
(
CH
)
2
→
Tautomerisation
(
CH
)
3
−
C
∣
∣
O
−
(
CH
)
3
(
Y
)