Q. Paramagnetism is directly related with presence of unpaired electron. As each unpaired electron has a magnetic moment associated with its spin angular momentum and orbital angular momentum.
For the series, the contribution of orbital angular momentum is effectively quenched and hence is of considerably importance. Thus, the magnetic moment is determined by the number of unpaired electrons and is calculated by using the spin only formula, i.e.

where number of unpaired electrons.
The paramagnetic metal ion among

 136  159 The d-and f-Block Elements Report Error

Solution:

and have configuration and therefore are paramagnetic in nature.