Q.
One litre of oxygen at a pressure of 1atm and two litres of nitrogen at a pressure of 0.5atm are introduced into a vessel of volume 1L . If there is no change in temperature, the final pressure of the mixture of gasses (in atm ) is
Ideal gas equation is given by, pV=nRT ...(i)
For oxygen, p=1atm,V=1L,n=nO2
Therefore Eq. (i) becomes 1×1=nO2RT ⇒nO2=RT1
For nitrogen p=0.5atm,V=2L,n=nN2 ∴0.5×2=nN2RT ⇒nN2=RT1
For mixture of gasses, PmixVmix=nmixRT
Here nmix=nO2+nN2 ∴RTPmixVmix=RT1+RT1 ⇒PmixVmix=2 Pmix=2