SO2 in presence of moisture acts as a bleaching agent. This is due to the reducing nature of SO2. SO2+2H2O→H2SO4+2H
Coloured matter +H→ colourless matter
Chlorine reacts with water forming HCl and HClO (hypochlorous acid). HClO is not so stable and decomposes giving nascent oxygen. Which is responsible for oxidising and bleaching properties of chlorine Cl2+H2O→HCl+HClO HClO→HCl+O
coloured matter + nascent oxygen → colourless matter