Q.
On heating an aldehyde with Fehling's reagent, a reddish brown precipitate is obtained due to the formation of
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AMUAMU 2018Aldehydes Ketones and Carboxylic Acids
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Solution:
When an aliphatic aldehyde is heated with Fehling's solution, the latter is reduced to give a red ppt. of cuprous oxide. During this reduction, the following reactions occu AldehydeRCHO+Fehling’s solution2CU2++5OH−→Carboxylate ionRCOO−+Cuprous oxide (Red ppt)Cu2O↓3H2O