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Tardigrade
Question
Chemistry
obtained by chlorination of n-butane, will be
Q. obtained by chlorination of n-butane, will be
2959
189
AIPMT
AIPMT 2001
Haloalkanes and Haloarenes
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A
meso form
15%
B
racemic mixture
68%
C
d-form
10%
D
I-form
8%
Solution:
Chlorination of
n
-butane takes place via free radical formation i.e.,
C
l
2
h
v
C
l
∙
+
C
l
∙
C
H
3
−
C
H
2
−
C
H
2
−
C
H
3
C
l
2
/
h
v
C
l
∙
may attack on either side and give a racemic mixture of
2
-chlorobutane which contain
50%
d
form and
50%
l
-form.