Q.
Number of anti aromatic compound in the following compound is______.
354
144
Organic Chemistry – Some Basic Principles and Techniques
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Answer: 4
Solution:
The molecules, which have 4nπ electrons are anti-aromatic compounds.
(a) has 4π-electrons
(b) has 6+2 (from oxygen atom) =8π electrons
(c) has 6π-electrons and one C-atom is sp3 hybridised hence it is non - aromatic.
(d) is aromatic
(e) has 4π-electrons as available lone pair with N - atom will not be delocalized in this conjugated system.
(f) has 12π-electrons.
Hence, (a), (b), (e) and (f) are anti-aromatic.