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Organic Chemistry – Some Basic Principles and Techniques
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Solution:
In 1,3 -diketones, the enol content is high due to stabilization of the enol both by H− bonding and resonance. Further since the C=O group in ketones is a much stronger electron withdrawing group than in esters, therefore, the enol content is much higher (76%) in acetylacetone than in ethyl acetoacetate (8%)