According to law of multiple proportions when two elements combine to form more than one compound, the fixed amount of one element combining with other element have simple whole number ratio.
[a] H2S and SO2 are not example of law of multiple proportion because elements are different.
[b] NH3 and NO2 are not examples of law of multiple proportion because elements are different.
[c] Na2S and Na2O
are not example of law of multiple proportion because elements are different.
[d] N2O and NO here 16 parts of oxygen react with 14 and 28 parts of nitrogen. 14:28 is 1:2 which is simple whole number ratio. ∴ It follows law of multiple proportion.