Q.
KBr crystallises in NaCl type of crystal lattice and its density is 2.75g/cm3. Number of unit cells of KBr present in a 1.00mm3 grain of KBr are
1935
205
ManipalManipal 2014The Solid State
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Solution:
In a unit cell of KBr, there are four formula units of KBr therefore,
Density (ρ)=6.023×1023×a34×119=2.75 a3=2.873×10−22cm3 =2.778×10−19mm3
Number of unit cells per mm3 =2.8731019=3.5×1018