Radius of nth Bohr's orbit of hydrogen like atom, rn∝Zn2
where, Z, is atomic number.
For first orbit, n=1 ∴rn∝Z1
Now, for radius of first orbit to be minimum, its atomic number must be greater. Here in the problem, atomic number Z is greater for doubly ionized lithium and is Z=3, Hence, for this system the radius of first orbit will be minimum.