If r0 is radius of first orbit in Hydrogen atom then radius of first orbit in Hydrogen like atoms is given by r=Zr0 .
For Hydrogen, Z=1
For Deuterium, Z=1
For singly ionized Helium He+ , Z=2
For doubly ionized Lithium Li2+ , Z=3 ∴ Radius of the first orbit, r is minimum for doubly ionized Lithium.