Q.
In which of the following reactions H2O2 acts as a reducing agent?
(1) H2O2+2H++2e−→2H2O
(2) H2O2−2e−→O2+2H+
(3) H2O2+2e−→2HO−
(4) H2O2+2OH−−2e−→O2+2H2O
The reducing agent oxidises itself by undergoing oxidation through the loss of electrons. Thus, reducing agent reduces other molecules by supplying electrons to them. (1)H2O2−1+2H++2e−→2H2O2
In this reaction, H2O2 undergoes reduction as O shows increase in oxidation number. (2)H2O2−1−2e−→O2o+2H+
In this reaction, H2O2 undergoes oxidation as it shows decrease in oxidation number. Thus, H2O2 acts as a reducing agent. (3)H2O2−1−2e−→2O−2H−
In this reaction, H2O2 undergoes reduction. (4)H2O2−1−2OH−−2e−→O2o+2H20
In this reaction, H2O2 undergoes reduction. Thus, acts as a reducing agent.