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Question
Chemistry
In which of the following reaction Kp > Kc ?
Q. In which of the following reaction
K
p
>
K
c
?
2111
191
AIIMS
AIIMS 2001
Equilibrium
Report Error
A
PC
l
3
+
C
l
2
→
PC
l
5
19%
B
H
2
+
I
2
→
2
H
I
26%
C
2
S
O
3
→
O
2
+
2
S
O
2
32%
D
N
2
+
3
H
2
→
2
N
H
3
23%
Solution:
K
p
=
K
c
(
RT
)
Δ
n
Δ
n = change in number of moles
If
Δ
n = positive then
K
p
will be greater than
K
c
.
PC
l
3
+
C
l
2
→
PC
l
5
,
Δ
n
=
1
−
2
=
−
1;
K
p
<
K
c
H
2
+
I
2
→
2
H
I
,
Δ
n
=
0;
K
p
=
K
c
2
S
O
3
→
O
2
+
2
S
O
2
,
Δ
n
=
1;
K
p
>
K
c
N
2
+
3
H
2
→
2
N
H
3
;
Δ
n
=
−
2;
K
p
<
K
c