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Question
Chemistry
In the preparation of chlorine by the electrolysis of brine, the reaction taking place at the anode is
Q. In the preparation of chlorine by the electrolysis of brine, the reaction taking place at the anode is
1995
203
TS EAMCET 2019
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A
C
l
−
(
a
q
)
⟶
2
1
C
l
2
(
g
)
+
e
−
B
N
a
+
(
a
q
)
+
e
−
⟶
N
a
(
s
)
C
O
2
(
g
)
+
4
H
+
+
4
e
−
⟶
4
H
2
O
(
I
)
D
H
+
(
a
q
)
+
e
−
⟶
2
1
H
2
(
g
)
Solution:
Chlorine can be manufactured by electrolysis of a sodium chloride solution (brine). The production of chlorine results in the co-products of caustic soda (sodium hydroxide,
N
a
O
H
) and hydrogen gas
(
H
2
)
.
At cathode
2
H
+
(
a
q
)
+
2
e
−
⟶
H
2
(
g
)
At anode
C
l
−
(
a
q
)
⟶
2
l
C
l
2
(
a
q
)
+
e
−
or
2
C
l
−
(
a
q
)
⟶
C
l
2
(
g
)
+
2
e
−