Q.
In the context of the Hall-Heroult process for the extraction of Al, which of the following statements is false ?
1920
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NTA AbhyasNTA Abhyas 2020The p-Block Elements - Part2
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Solution:
Hall heroult process:
In the Hall-Héroult process the following simplified reactions take place at the carbon electrodes:
Cathode: Al3++3e−1→Al
Anode: O2−+C→CO+2e−
Overall:
Al2O3+3C→2Al+3CO
And 2Al2O3+3C→4Al+3CO2
In reality, much more CO2 is formed at the anode than CO:
Cryolite ( Na3AlF6 ) lowers the melting point of the mixture and make it more conductive in nature so as to carry out electrolysis of the ore in Hall-Heroult process.