Q.
In Dumas method for the estimation of N2, the sample is heated with copper oxide and the gas evolved is passed over :
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JEE MainJEE Main 2023Organic Chemistry – Some Basic Principles and Techniques
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Solution:
Duma's method.
The nitrogen containing organic compound, when heated with CuO in a atmosphere of CO2, yields free N2 in addition to CO2 and H2O. CxHyNz+(2x+2y)CuO→ xCO2+2yH2O+2zN2+(2x+2y)Cu
Traces of nitrogen oxides formed, if any, are reduced to nitrogen by passing the gaseous mixture over heated copper gauze.