In aqueous solutions, amino acids mostly exist as H3N+−CHRCOO−(zwitter ion).
In aqueous solution, amino acids exist in two forms. A very small fraction of amino acid molecules will be neutral, with a deprotonated amino groum and a protonated carboxylic acid group. However, the overwhelming majority of molecules will be in a zwitterion tautomer, with a positive charge on the protonated amino group and a negative charge on the deprotonated carboxylate group.