Q.
In a sample of H atoms, electrons make transition from fifth state to ground state producing all possible wavelengths, then the value of the fifth highest energy line (in eV ) is
In the hydrogen spectrum, Balmer series lines have second highest energy. ⇒5th highest energy line belongs to 5→2 transition. ⇒ΔE=2.86eV
Clearly 5th highest line is 5→2 ⇒ΔE=3.4−0.54=2.86eV.