Q.
In a reaction, Na2S2O3 is converted to Na2S4O6,
equivalent weight of Na2S2O3 for this reaction is (mol. wt of Na2S2O3=M)
2556
191
Some Basic Concepts of Chemistry
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Solution:
2Na2S2O3→Na2S4O6+2Na
Mol. wt. of Na2S2O3=M
For this reaction, oxidation state of 1 atom of sulphur on the left side is +2 and on the right hand side of the equation, is 2.5. So, difference is 0.5.
Valency factor = no. of atoms × change in oxidation number =2×0.5=1 ∴ Equivalent weight =M