Here, X=PT=p1+p2= Total pressure of the solution. p1 and p2 is the partial pressure of component 1 and 2 respectively. Y=x2= mole fraction of component 2 in the liquid phase. Z=y2= mole fraction of component 2 in the vapour phase.
When mole fraction of component 2 in the liquid phase is 0 then mole fraction of component 2 in the vapour phase is also 0 which means the liquid is pure of component 1 only.