Q.
If the value of CP for nitrogen gas is 7JK−1mol−1, then the value of ΔH on heating 28g of nitrogen gas from 0∘C to 100∘C at constant pressure will be
Heat of reaction at constant pressure is given by the equation
Here ΔH=nCp(T2−T1) Cp=7JK−1mol−1
weight of N2gas=28g T1=0∘C=273+0=273K T2=100∘C=273+100=373K
Number of moles = molecular weight of nitrogen weight of nitrogen =1428=2
Now by using ΔH=nCP(T2−T1) =2×7(373−273) ΔH=14×100=1400J