Let total energy of hydrogen like atom at ground state =−E
So, 1 st excitation
Energy =E2nd−E1st 15eV=(22−E)−[12E] (∵ First excitation potential is given) ⇒43E=15eV ⇒E=315×4eV=20eV
Now, the third excitation energy E3=E4th−E1st =(42−E)−[12E] E3=+1615E
Now, putting the value of E, we get E3=1615×20=475eV