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Chemistry
If for H2(g)+(1/2) O2(g) arrow H2 O(g), Δ H1 is the enthalpy of reaction and for H2(g)+(1/2) O2(g) arrow H2 O(l) Δ H2 is enthalpy of reaction, then
Q. If for
H
2
(
g
)
+
2
1
O
2
(
g
)
→
H
2
O
(
g
)
,
Δ
H
1
is the enthalpy of reaction and for
H
2
(
g
)
+
2
1
O
2
(
g
)
→
H
2
O
(
l
)
Δ
H
2
is enthalpy of reaction, then
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178
BHU
BHU 2010
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A
Δ
H
1
>
Δ
H
2
B
Δ
H
1
=
Δ
H
2
C
Δ
H
1
<
Δ
H
2
D
Δ
H
1
+
Δ
H
2
=
0
Solution:
In the process,
H
2
(
g
)
+
2
1
O
2
(
g
)
⟶
H
2
O
(
l
)
, heat is evolved because state is changing from gaseous to liquid, ie, the process is exothermic.
Hence,
<
b
r
/
>
Δ
H
1
<
Δ
H
2