According to Brewster law, when a beam of unpolarised light is reflected from a transparent medium, the reflected light is completely plane polarised at a certain of incidence, called angle of polarisation.
Given, Brewster's angle, θ=60∘
We know that, μ=tanθ ...(i) ⇒μ=tan60∘=3
Now, μ=sinrsini ⇒sinr=μsini=3sin60∘⇒33/2 ⇒sinr=21 ⇒r=sin−1(21)=30∘
Angle of deviation inside the glass, d=i−r=60∘−30∘=30∘