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Chemistry
If a LPG cylinder contains mixture of butane and isobutane, then the amount of oxygen that would be required for combustion of 1 kg of it will be
Q. If a
L
PG
cylinder contains mixture of butane and isobutane, then the amount of oxygen that would be required for combustion of
1
k
g
of it will be
1374
191
UPSEE
UPSEE 2013
Thermodynamics
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A
2.50
×
1
0
3
g
B
4.50
×
1
0
3
g
C
1.80
×
1
0
3
g
D
3.58
×
1
0
3
g
Solution:
The standard enthalpy of combustion of butane
C
4
H
10
(both
n
-and iso butanes are main constituents of cooking gas). representing the combustion of 1 mole of butane in the presence of oxygen, may be representing represented as follows
1 mol
C
4
H
10
(
g
)
+
12
13
m
o
l
2
13
O
2
(
g
)
→
4
C
O
2
(
g
)
+
5
H
2
O
(
l
)
;
Δ
c
H
∘
=
−
2658.0
k
J
m
o
l
−
1
(
58
g
)
(
2
13
×
32
=
208
g
)
∴
O
2
required for
1
k
g
butane
=
58
208
×
1000
g
=
3.58
×
1
0
3
g