Given, 3p+2q=i+j+k…(i)
and 3p−2q=i−j−k…(ii)
On adding Eqs. (i) and (ii), we get 6p=2i ∴p=3i
On subtracting Eq. (ii) from Eq. (i), we get 4q=2(j+k) ⇒q=21(j+k)
Let θ be the angle between p and q, then p⋅q=∣p∣∣q∣cosθ ⇒cosθ=∣p∣∣q∣p⋅q ⇒cosθ=61∣p∣∣q∣i⋅(j+k)=0 =cos90∘ ∴θ=90∘ =2π