Q.
Identify the total number of compounds from the following which will yield monocarboxylic acid on oxidation with KMnO4 in acidic medium.
223
117
Aldehydes Ketones and Carboxylic Acids
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Answer: 3
Solution:
In case of aromatic compounds, the complete side chain (consisting of an alkyl group) is oxidised to −COOH group irrespective of the length of the chain except in case of tert-butylbenzene. In case of cyclohexene, it gives dicarboxylic acid.
∴ Compounds (i), (ii) and (v) will yield monocarboxylic acids on oxidation with KMnO4 in acidic medium.