Q.
Identify the substance whose 0.1M solution is basic?
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J & K CETJ & K CET 2010Equilibrium
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Solution:
Sodium acetate is a salt of strong base (NaOH) and weak acid (CH3COOH).
In aqueous solution it gets hydrolysed as CH3COONa+H2O→CH3COOH+NaOH
or CH3COO−+Na++H2O→CH3COOH +Na++OH−or CH3COO−+H2O→CH3COOH+OH−
Because of the excess of [OH−]in aqueous solution, its solution is basic in nature.
Aqueous solution of salt of strong acid and weak base is acidic and that of strong
acid and strong base is neutral.