Q. Identify the correct statements from the following.
(1) The dipole moment of and is zero.
(2) The dipole moment of is higher than the dipole moment of .
(3) The dipole moment of is lower than the dipole moment of .

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Solution:

1 . The molecule has a symmetrical trigonal planar geometry, the moment of any two dipoles is equal in magnitude but opposite in direction to the moment of the molecule is zero. Same as .

2. In is more electronegative than so, pulls the electrons from H towards itself so, the direction of moment due to the bonds is in the same direction as that of the lone pair of electrons on nitrogen.

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But in case of [lone pair] moment is in the opposite direction to the bond moments.

Thus, has smaller net dipole moment.

3. Size of I-atom is more than of Cl-atom and electronegativity of I-atom is less than of Cl-atom. Hence, HI has lower dipole-moment than HCl.