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Question
Chemistry
Ice crystallises in a hexagonal lattice. At the low temperature, the lattice constants were a = 4.53 mathringA and b = 7.41 mathringA. How many H2O molecules are contained in a unit cell? [d(ice) = 0.92 g / cm]
Q. Ice crystallises in a hexagonal lattice. At the low temperature, the lattice constants were
a
=
4.53
A
˚
and
b
=
7.41
A
˚
. How many
H
2
O
molecules are contained in a unit cell?
[
d
(
i
ce
)
=
0.92
g
/
c
m
]
1824
195
UPSEE
UPSEE 2014
The Solid State
Report Error
A
4
B
3
C
2
D
1
Solution:
Volume of the unit cell,
V
=
area of rhombus base
×
b
=
(
a
2
sin
6
0
∘
)
×
b
=
(
4.53
)
2
×
2
3
×
7.41
×
1
0
−
24
c
m
3
=
132
×
1
0
−
24
c
m
3
Thus, the mass of unit cell
=
V
×
d
=
132
×
1
0
−
24
×
0.92
×
6.02
×
1
0
23
=
73
g
This is close to 4 times the molecular weight of
H
2
O
.
So, there are four molecules of
H
2
O
per unit.