Q.
Hyperconjugation is most useful for stabilising which of the following carbocations?
2408
210
KEAMKEAM 2010Organic Chemistry – Some Basic Principles and Techniques
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Solution:
On the basis of hyperconjugation, stability order of different alkyl carbocations is 3∘>2∘>1∘>methyl
In t-butyl cation, the C-atom bearing the positive charge is attached to three methyl groups, thus it will have maximum hyperconjugative structures, which give it maximum stability.