Preparation of Hydrogen peroxide includes laboratory method and industrial method.
In industrial method Hydrogen peroxide ia prepared from electrolytic process, in which 30% ice cold sulphuric acid is electrolyzed at high current density, then, peroxydisulphate is obtained,which on hydrolysis gives hydrogen peroxide.
Following reaction take place on electrolysis of sulphuric acid. 2HSO4−→H2S2O8+2e−H2S2O8+H2O→H2O2+H2SO4
Thus answer is option 2