From below structures we can see that all are 6 member ring except B2H6 and in case of H3P3O9 hybridisation of P is SP3, which is not a planar structure. All other are 6 members planar structure. SP2 hybridisation with planar structure. SP2 hybridisation with planar structure. SP2 hybridisation with planar structure. SP2 hybridisation with planar structure. SP3 hybridization of each Phosphorous.