The balanced equation of acidified FeSO4 with KMnO4 is 2KMnO4+8H2SO4ferroussulphate+10FeSO4 K2SO4+2MnSO4ferricsulphate+5Fe2(SO4)3+8H2O ∵ 2 mole of KMn04 oxidised = 10 moles of FeSO4∴ 1 mole of KMn04 will oxidise =210=5 moles of FeSO4