2C(s)+2O2(g)⟶2CO2(g); ΔH=−787kJ…(i) H2(g)+21O2(g)⟶H2O(l); ΔH=−286kJ…(ii) C2H2(g)+221O2(g)⟶2CO2(g)+H2O(l) ΔH=−1310kJ…(iii)
Add the Eqs. (i) and (ii) and subtract Eq. (iii) from them. 2C+H2⟶C2H2−787−286+1310 2C+H2⟶C2H2−1073+1310 2C+H2⟶C2H2+237
Hence, the heat of formation of acetylene is + 237kJ.