Q.
Four gases P,Q,R and S have almost same values of ‘b’ but their ‘a’ values (a, b are van der Waals constants) are in the order Q<R<S<P. At a particular temperature, among the four gases the most easily liquefiable one is
Higher the value of a, more will be the tendency to get liquefy. Since, value of a is highest for P1 thus, P is the most liquefiable gas among the given.