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Tardigrade
Question
Chemistry
For the reaction 2NO2(g) leftharpoons 2 NO(g) + O2(g) (Kc = 1.8×10-6 at 184°C) (R = 0.00831 k J/(mol. K)) When Kp and Kc are compared at 184° C it is found that :
Q. For the reaction
2
N
O
2
(
g
)
⇌
2
NO
(
g
)
+
O
2
(
g
)
(
K
c
=
1.8
×
1
0
−
6
a
t
18
4
∘
C
)
(
R
=
0.00831
k
J
/
(
m
o
l
.
K
)
)
When
K
p
and
K
c
are compared at
18
4
∘
C it is found that :
4705
226
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AIEEE 2005
Equilibrium
Report Error
A
whether
K
p
is greater than, less than or equal to
K
c
depends upon the total gas pressure
9%
B
K
p
=
K
c
21%
C
K
p
is less than
K
c
13%
D
K
p
is greater than
K
c
57%
Solution:
2
N
O
2
(
g
)
⇌
2
NO
(
g
)
+
O
2
(
g
)
K
c
=
1.8
×
1
0
−
6
a
t
18
4
∘
C
(
=
457
K
)
R
=
0.00831
k
J
m
o
l
−
1
K
−
1
K
p
=
K
c
(
RT
)
Δ
n
g
where,
Δ
n
g
=
(gaseous products - gaseous reactants)
=
3
−
2
=
1
∴
K
p
=
1.8
×
1
0
−
6
×
0.00831
×
457
=
6.836
×
1
0
−
6
>
1.8
×
1
0
−
6
Thus
K
p
>
K
c