H2PO4−+H2OHPO42−+acidH3O+ H2PO4−+H2OH3PO4+ base OH−
Similarly, HPO42−+H2OPO43−+ acid H+HPO42−+H2OH2PO4−+ base OH− ∴H2PO4− and HPO42− are amphiprotic anions which can undergo ionisation to form H+ions and can undergo hydrolysis to form OH−ions.
Thus, for preparing a buffer solution of pH=7.0,
the buffer system of weak acid H2PO4− and its conjugated base HO42− are used.