For an ideal gas CV=∂T∂U∣v=constant
or CV=dTdU
Also, for 1 mole of gas, CV=2f.R
where, f= degree of freedom.
Hence, we have 2fR=dTdU
Here, U=25pV+C=25RT+C
[∴ one mole of gas is considered]
So, 2fR=DTd(25RT+C) ⇒2fR=25R⇒f=5
Now, using γ=1+γ2
We have, γ=1+52 ⇒γ=57
So, equation of adiabats can be written pVγ=constant ⇒pV15= constant ⇒p5V7= constant