Extraction of Cu from copper pyrites (CuFeS2) involves. → Crushing followed by concentration of the ore by froth flotation → removal of iron as slag FeO+acidic fluxSiO2⟶SlagFeSiO3 → Self-reduction step to produce 'blister copper' following evolution of SO2, Cu2S+2Cu2O⟶bliscer copper6Cu+SO2↑