Q.
During a reversible adiabatic process, the pressure of a gas is found to be proportional to the cube of its absolute temperature. The ratio CVCP for the gas is
According to question, during a reversible adiabatic process the pressure of a gas is found to be proportional to the cube of its absolute temperature.
p∝T3
pT−3= constant .... (ii)
Equating equation (i) and (ii), we get
1−γγ=−3
γ=−3(1−γ)
γ=−3+3γ
−2γ=−3
γ=23
As we know, the ratio of molar heat capacities at constant pressure and constant volume is respectively by γ. So, the ratio of CvCp for the gas is 23.