Depression in freezing point is a colligative property, it means that as the number of particles (ions) of solute increases, freezing point of the solution decreases.
Sucrose ⟶ not ionised KCl⇌2ionsK++Cl− BaCl2⇌3 ions Ba2++2Cl− AlCl3⇌4 ions Al3++3Cl−
Hence, the correct order of freezing point is
Sucrose >KCl>BaCl2>AlCl3