Q.
Compound A and B are treated with dil.HCl separately. The gases liberated are Y and Z respectively. Y turns acidified dichromate paper green while Z turns lead acetate
paper black. The compound A and B are respectively.
Gas (Y)SO2 which can be obtained from Na2SO3(A) and gas (Z) is H2S which can be obtained from Na2S(B).
This can be easily understood by the following reactions. (A)Na2SO3+2HCl⟶2NaCl+(Y)SO2H2O (B)Na2S+2HCl⟶2NaCl+(Z)H2O K2Cr2O7+H2SO4+3SO2⟶K2SO4+greenCr2(SO4)3+H2O Pb(CH3COO)2+H2S⟶ black PbS↓+2CH3COOH