The partial pressure of oxygen in atmospheric air is higher than that of oxygen in alveolar air. In atmospheric air, pO2 is about 15,mmHg. In alveolar air, it is about 104mmHg.
The partial pressure of CO2 in atmospheric air is lesser than that of CO2 in alveolar air. In atmospheric air, pCO2 is about 0.3mmHg. In alveolar air, it is about 40mmHg.