Colour of the bead in borax bead test is mainly due to the formation of

Question

Colour of the bead in borax bead test is mainly due to the formation of (A) metal oxides (B) boron oxides (C) metal metaborates (D) elemental boron

Tardigrade Admin · Accepted Answer

Colour of the bead in borax bead test is mainly due to the formation of metal metaborates. In this process, borax on strong heating loses its water of crystallisation and swells up to form puffy mass.

On further heating it melts into clear liquid that solidifies to transparent glass like bead that consists of sodium metaborate

(N a B O_{2})

and basic anhydride

(B_{2} O_{3})

.

N a_{2} B_{4} O_{7} ⟶ Heat N a_{2} B_{4} O_{7} + 10 H_{2} O

N a_{2} B_{4} O_{7} ⟶ Heat Transparent borax bead/ glassy bead 2 N a B O_{2} + B_{2} O_{3}

Now, whenever a coloured salt containing cations like

N i^{2 +}, C o^{2 +}, C r^{3 +}

etc. is heated with borax bead on platinum wire, the salt decomposes to form corresponding metal oxide that combines with

B_{2} O_{3}

to form coloured metaborates. This test is called borax bead test.

e.g.

C o S O_{4} ⟶ Δ C o O + S O_{3}

C o O + B_{2} O_{3} ⟶ Δ Cobalt metaborate (blue) C o (B O_{2})_{2}

Q. Colour of the bead in borax bead test is mainly due to the formation of

metal oxides

boron oxides

metal metaborates

elemental boron