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Question
Chemistry
[Co(NH3)5Br)] SO4 and [Co(NH3)5SO4] Br are examples of which type of isomerism ?
Q.
[
C
o
(
N
H
3
)
5
B
r
)]
S
O
4
and
[
C
o
(
N
H
3
)
5
S
O
4
]
B
r
are examples of which type of isomerism ?
4341
237
AMU
AMU 2013
Coordination Compounds
Report Error
A
Linkage
17%
B
Geometrical
0%
C
Ionisation
83%
D
Optical
0%
Solution:
[
C
o
(
N
H
3
)
5
B
r
]
S
O
4
and
[
C
o
(
N
H
3
)
5
S
O
4
]
B
r
are examples of ionisation isomerism. This form of isomerism arises when the counter ion in a complex salt is itself a potential ligand and can displace a ligand which can then become the counter ion.