The acidity of carboxylic acids depends upon the nature of the alkyl group attached to COOH . The presence of an electron-withdrawing ( −I effect) group weakens the OH bond in the acid and increases the acidity, while the presence of an electron releasing ( +I effect) group strengthens the OH bond of acid and thus, decreases the acidity. Thus, the weakest acid is, 2−methylpropanoicacidCH3−CHCH3∣−COOH